Grammer, 42, will team with the cable news network's Showbiz Tonight anchors AJ Hammer and Brooke Anderson to provide live red-carpet fashion commentary on Road Gold.
U.S. & World
News from around the country and around the globe
"We can't wait to get Camille's unabashed take on Hollywood's biggest night," said a CNN executive producer in a statement to PopEater.
Grammer's divorce to the Fraiser star was finalized on February 10. Kelsey Grammer plants to marry fiance Kayte Walsh, who is pregnant with his child.